I have been hitting “Network Error 99” and the Desktop client freezing up since upgrading to NextCloud 25. I finally found a fix discussed in GitHub issue 5094, in summary this is what fixed it for me:
On the client, disable any upload speed limits
On the server, edit config.php to add the line 'bulkupload.enabled' => false,
From the discussions on GitHub, it sounds like the upload speed limit and bulk upload features are buggy in the latest server/desktop releases.
This solved it for me perfectly. Had to wait forever for Nextcloud to revalidate the sync, but then it suddenly finished and got the big green checkmark.
I have the same problem, I cannot find a solution and PLUS since I’ve installed Nextcloud I have a lot of problems with windows app icons and preview of a lot of files in other windows apps.
I already wrote to Nextcloud with their website form but no-one still answered me… I’m so upset!