How to use own Intranet penetration solution without the default configured stun server

Have you tried to set it up and putting an arbitrary IP into the setting that is not resolvable? E.g. 192.168.1.101 and no machine is listening on that machine.

At worst you could install a local STUN server inside the IP range and use that one.
Honestly, I am unsure if the process needs some signaling service internally that bases on the services. But this is just guessing.